In this work, carbon xerogels (CXGs) doped with nitrogen or sulfur have been investigated as DSSC counter electrodes. CXGs have been prepared by a sol-gel method from resorcinol and formaldehyde and subsequent carbonization. Nitrogen doping has been carried out by introducing melamine into the synthesis process along with resorcinol and formaldehyde, while sulfur has been incorporated by direct reaction of the carbon material with elemental sulfur. The counter electrodes for DSSCs have been prepared by airbrushing on conductive glass (fluorine-doped tin oxide, FTO), and their electrochemical behavior has been evaluated, observing that the introduction of heteroatoms such as nitrogen or sulfur leads to an improvement in efficiency compared to the undoped material thanks to a decrease in charge transfer resistance.
Influence of Nitrogen and Sulfur Doping of Carbon Xerogels on the Performance and Stability of Counter Electrodes in Dye Sensitized Solar Cells
Girolamo M;Baglio V
2022
Abstract
In this work, carbon xerogels (CXGs) doped with nitrogen or sulfur have been investigated as DSSC counter electrodes. CXGs have been prepared by a sol-gel method from resorcinol and formaldehyde and subsequent carbonization. Nitrogen doping has been carried out by introducing melamine into the synthesis process along with resorcinol and formaldehyde, while sulfur has been incorporated by direct reaction of the carbon material with elemental sulfur. The counter electrodes for DSSCs have been prepared by airbrushing on conductive glass (fluorine-doped tin oxide, FTO), and their electrochemical behavior has been evaluated, observing that the introduction of heteroatoms such as nitrogen or sulfur leads to an improvement in efficiency compared to the undoped material thanks to a decrease in charge transfer resistance.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.