The 2:1 reaction of [Ru(H2O)2(NH3)5]2+ with 1,2,4,5-tetrazine (tz) gives rise to the formation of the dinuclear complex ion [{Ru(NH3)5}2(Ý-tz-N 1:N 4)]4+. Its tetraphenylborate and hexafluoro-phosphate salts have been fully characterized; the X-ray structure of the former has also been determined.
Ý -1,2,4,5-Tetrazine-N 1:N4-bis(pentaammineruthenium) tetracation: Synthesis and X-ray structure
Calucci Lucia;
2007
Abstract
The 2:1 reaction of [Ru(H2O)2(NH3)5]2+ with 1,2,4,5-tetrazine (tz) gives rise to the formation of the dinuclear complex ion [{Ru(NH3)5}2(Ý-tz-N 1:N 4)]4+. Its tetraphenylborate and hexafluoro-phosphate salts have been fully characterized; the X-ray structure of the former has also been determined.File in questo prodotto:
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