Here we present the formation of an iminothioindoxyl (ITI)⊂Cage complex that retains the photochemical properties of the photoswitch within a confined environment in water. At the same time, besides ultrafast switching inside the cage, the ITI photoswitch displays an intriguing bifurcation of the excited state isomerization pathway when encapsulated.
Modulation of the isomerization of iminothioindoxyl switches by supramolecular confinement
Doria, Sandra;Di Donato, Mariangela;
2024
Abstract
Here we present the formation of an iminothioindoxyl (ITI)⊂Cage complex that retains the photochemical properties of the photoswitch within a confined environment in water. At the same time, besides ultrafast switching inside the cage, the ITI photoswitch displays an intriguing bifurcation of the excited state isomerization pathway when encapsulated.File in questo prodotto:
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Chem. Commun., 2024,60, 9388-9391.pdf
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