Formation of the vinylogous bridge between adjacent pyrrole rings (A and B) in the reaction of 5,10,15-triphenylcorrole with CI4 affords the corresponding hemiporphycene (see structure; N blue, I pink, C white, H green). This approach allows a facile preparation of functionalized hemiporphycenes.
Hemiporphycene from the expansion of a corrole ring
Paolesse R;
2005
Abstract
Formation of the vinylogous bridge between adjacent pyrrole rings (A and B) in the reaction of 5,10,15-triphenylcorrole with CI4 affords the corresponding hemiporphycene (see structure; N blue, I pink, C white, H green). This approach allows a facile preparation of functionalized hemiporphycenes.File in questo prodotto:
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