The radiation-induced polymerization of isoprene was made on its inclusion (or clathrate) complex with deoxycholic acid (DOCA) at 150 and 300kGy. The microstructure of the resulting polyisoprene (PIP) was studied by FTIR spectroscopy and found fully comparable to that of PIP prepared by emulsion polymerization by a free radical initiator. Thus, the 1,4-trans content was found to be 48% and that of 1,4-cis units was 28% of the polymer structure: the remaining are being 1,2 and 3,4 units. The PIP irregular microstructure was justified in terms of monomer dynamics inside the DOCA channels. PIP from inclusion polymerization is fully amorphous as studied by differential thermal analysis (DTA) in comparison to an authentic sample of trans-1,4-polyisoprene, which instead has a crystalline melting point of 71.5 degrees C. The inclusion complex of PIP with DOCA (PIP@DOCA) shows a DTA melting point of 194.4 degrees C, 12.4 degrees C higher than the melting point of pure DOCA. PIP isolated from inclusion polymerization from DOCA and its complex PIP@DOCA was studied also by thermogravimetry (TGA) and differential thermogravimetry (DTG).
Inclusion polymerization of isoprene in deoxycholic acid
P Ragni;A Rosati;O Ursini
2009
Abstract
The radiation-induced polymerization of isoprene was made on its inclusion (or clathrate) complex with deoxycholic acid (DOCA) at 150 and 300kGy. The microstructure of the resulting polyisoprene (PIP) was studied by FTIR spectroscopy and found fully comparable to that of PIP prepared by emulsion polymerization by a free radical initiator. Thus, the 1,4-trans content was found to be 48% and that of 1,4-cis units was 28% of the polymer structure: the remaining are being 1,2 and 3,4 units. The PIP irregular microstructure was justified in terms of monomer dynamics inside the DOCA channels. PIP from inclusion polymerization is fully amorphous as studied by differential thermal analysis (DTA) in comparison to an authentic sample of trans-1,4-polyisoprene, which instead has a crystalline melting point of 71.5 degrees C. The inclusion complex of PIP with DOCA (PIP@DOCA) shows a DTA melting point of 194.4 degrees C, 12.4 degrees C higher than the melting point of pure DOCA. PIP isolated from inclusion polymerization from DOCA and its complex PIP@DOCA was studied also by thermogravimetry (TGA) and differential thermogravimetry (DTG).I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
