The complex [(PP,)OsH(N,)]BPh, is a catalyst precursor for the regio- and stereoselective dimerization of HC=CR (R = Ph, SiMe,) to (Z)-1,4-disubstituted-but-3-en-l-ynes (PP3 = P(CH2CH2PPh&). In the presence of HZ0 or GH,OH, the catalytic reaction with HC=CSiMe, selectively gives but-3-en-1-ynyl-trimethylsilane. A detailed study under different experimental conditions, the detection of some intermediates, and the use of isolated complexes in independent reactions, taken altogether, permit mechanistic conclusions which account for the observed products. A key-role is played by (vinylidene)u-alkynyl complexes which transform into q3-butenynyl derivatives via intramolecular C-C bond formation. The Os(I1) v3-butenynyl complexes are likely reagents in the rate determining step of the catalytic cycle, and produce free (Z)-1,4-disubstituted-but-3-en-1-ynes upon u-bond metathesis reaction with HC=CR. The 16-electron fragments [(PP,)OsX]+ (X=H, Cl, C=CR) are capable of promoting the 1-alkyne to vinylidene tautomerism. In particular, the (vinylidene)hydride [(PP,)OsH{C=C(H)- SiMe,}]BPh, has been isolated and properly characterized. Since the stoichiometric reaction of the latter compound with HC-CSiMe3 gives vinyltrimethylsilane, the formation of (vinylidene)hydride species is suggested to be an effective step, alternative to 1-alkyne insertion, in the reduction of I-alkynes to alkenes assisted by hydrido metal complexes.
Regio- and Stereoselective Dimerization of 1-Alkynes Catalyzed by an Os(II) Complex
Barbaro Pierluigi;Bianchini Claudio;Peruzzini Maurizio;
1994
Abstract
The complex [(PP,)OsH(N,)]BPh, is a catalyst precursor for the regio- and stereoselective dimerization of HC=CR (R = Ph, SiMe,) to (Z)-1,4-disubstituted-but-3-en-l-ynes (PP3 = P(CH2CH2PPh&). In the presence of HZ0 or GH,OH, the catalytic reaction with HC=CSiMe, selectively gives but-3-en-1-ynyl-trimethylsilane. A detailed study under different experimental conditions, the detection of some intermediates, and the use of isolated complexes in independent reactions, taken altogether, permit mechanistic conclusions which account for the observed products. A key-role is played by (vinylidene)u-alkynyl complexes which transform into q3-butenynyl derivatives via intramolecular C-C bond formation. The Os(I1) v3-butenynyl complexes are likely reagents in the rate determining step of the catalytic cycle, and produce free (Z)-1,4-disubstituted-but-3-en-1-ynes upon u-bond metathesis reaction with HC=CR. The 16-electron fragments [(PP,)OsX]+ (X=H, Cl, C=CR) are capable of promoting the 1-alkyne to vinylidene tautomerism. In particular, the (vinylidene)hydride [(PP,)OsH{C=C(H)- SiMe,}]BPh, has been isolated and properly characterized. Since the stoichiometric reaction of the latter compound with HC-CSiMe3 gives vinyltrimethylsilane, the formation of (vinylidene)hydride species is suggested to be an effective step, alternative to 1-alkyne insertion, in the reduction of I-alkynes to alkenes assisted by hydrido metal complexes.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
