The nitration process of salicylic acid for the production of the important intermediate 5-nitrosalicylic acid is studied from thermokinetic and safety points of view. Investigations carried out by considering, as process deviations, the loss of the thermal control point out the possibility of runaway phenomena due to the occurrence of polynitration reactions. Isothermal experiments are carried out in various conditions to assess the involved reaction network and reaction kinetics. © 2005 Elsevier B.V. All rights reserved.
Kinetic And Safety Assessment for Salicylic Acid Nitration By Nitric acid/Acetic Acid System
Di Somma I;Sanchirico R
2006
Abstract
The nitration process of salicylic acid for the production of the important intermediate 5-nitrosalicylic acid is studied from thermokinetic and safety points of view. Investigations carried out by considering, as process deviations, the loss of the thermal control point out the possibility of runaway phenomena due to the occurrence of polynitration reactions. Isothermal experiments are carried out in various conditions to assess the involved reaction network and reaction kinetics. © 2005 Elsevier B.V. All rights reserved.File in questo prodotto:
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