In the current work we investigate the route of interaction of a newly synthesized family of zinc complexes with HS- by a plethora of different spectroscopic techniques. A computational analysis on the time dependent density functional theory (TD-DFT) level explored the overall fluorescence properties of the title complexes and their different fluorescence responses to HS-. Time-resolved fluorescence experiments were also performed and highlight the great potential of the current systems to be implemented as HS- fluorescent sensors.
Salen, salan and salalen zinc(ii) complexes in the interaction with HS−: time-resolved fluorescence applications
Varriale, Antonio;D'Auria, Sabato;
2023
Abstract
In the current work we investigate the route of interaction of a newly synthesized family of zinc complexes with HS- by a plethora of different spectroscopic techniques. A computational analysis on the time dependent density functional theory (TD-DFT) level explored the overall fluorescence properties of the title complexes and their different fluorescence responses to HS-. Time-resolved fluorescence experiments were also performed and highlight the great potential of the current systems to be implemented as HS- fluorescent sensors.File in questo prodotto:
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