The electrodeposition of polymeric films of a fluorene-bridged dicarbazole monomer containing linear polyfluorinated side chains is here investigated, with regard to the use of on-site electrochemically generated gas bubbles from hydrazine or water as soft template agent. The interconnected effects of the bubbles precursor and electrochemical parameters employed on the morphology and water wettability properties of the electrodeposited films are demonstrated. The use of N2H4 as a gas precursor proved to be a versatile, complementary alternative to water, which allows a finer tuning of the electrodeposited polymer film morphology

A comparative study of the effects of gas bubbles generated from hydrazine or/and water on the surface morphology and hydrophobicity of electrodeposited polymer films

Pozzi G.
Penultimo
;
2023

Abstract

The electrodeposition of polymeric films of a fluorene-bridged dicarbazole monomer containing linear polyfluorinated side chains is here investigated, with regard to the use of on-site electrochemically generated gas bubbles from hydrazine or water as soft template agent. The interconnected effects of the bubbles precursor and electrochemical parameters employed on the morphology and water wettability properties of the electrodeposited films are demonstrated. The use of N2H4 as a gas precursor proved to be a versatile, complementary alternative to water, which allows a finer tuning of the electrodeposited polymer film morphology
2023
Istituto di Scienze e Tecnologie Chimiche "Giulio Natta" - SCITEC - Sede Secondaria Milano - Via C. Golgi
Soft-template, Fluorinated polymers, Electrodeposition, Surface morphology tuning, Bubbles precursor, Superhydrophobic property
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/512873
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