We present evidence that the concurrent existence of two populations of particles with different effective diameters is not a prerequisite for the occurrence of anomalous phase behaviors in systems of particles interacting through spherically symmetric unbounded potentials. Our results show that an extremely weak softening of the interparticle repulsion, which yields a single nearest-neighbor separation, is able to originate a wide spectrum of unconventional features including reentrant melting, solid polymorphism, as well as thermodynamic, dynamic, and structural anomalies. These findings extend the possibility of anomalous phase behavior to a class of systems much broader than currently assumed.

Anomalous phase behavior in a model fluid with only one type of local structure

Saija F;
2010

Abstract

We present evidence that the concurrent existence of two populations of particles with different effective diameters is not a prerequisite for the occurrence of anomalous phase behaviors in systems of particles interacting through spherically symmetric unbounded potentials. Our results show that an extremely weak softening of the interparticle repulsion, which yields a single nearest-neighbor separation, is able to originate a wide spectrum of unconventional features including reentrant melting, solid polymorphism, as well as thermodynamic, dynamic, and structural anomalies. These findings extend the possibility of anomalous phase behavior to a class of systems much broader than currently assumed.
2010
Istituto per i Processi Chimico-Fisici - IPCF
anomalous melting
solid-solid transition
high-pressure phase diagrams of the elements
File in questo prodotto:
File Dimensione Formato  
prod_40270-doc_2336.pdf

non disponibili

Descrizione: Anomalous phase behavior in a model fluid with only one type of local structure
Dimensione 328.31 kB
Formato Adobe PDF
328.31 kB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/51621
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? 43
social impact