A novel 2D-GO@WS2 electrochemical platform for the determination of thiram fungicide

In this paper, the determination of Thiram fungicide by a novel modified screen-printed carbon electrode (SPCE) fabricated modifying the working electrode (WE) with 2D-GO/WS2 nanohybrid composites, is reported. Scanning electron microscopy (SEM), Raman spectroscopy, and fluorescence analysis (PL) were used to reveal the morphological and microstructural characteristics of the 2D-GO/WS2 nanohybrids with different graphene oxide:tungsten disulphide (GO:WS2) ratio. Electrochemical characterization demonstrated that the 2D-WS2/GO nanohybrids having a GO:WS2 ratio = 2:1 shows the highest electrocatalytic activity towards oxidation of Thiram. The developed sensor permits the quantification of Thiram in the linear range 0.083-0.33 µmol/L with a limit of detection (LOD) of 0.02 µmol/L, which is below the legal limits for this fungicide in drinking water or foods.