Photocatalytic H2 generation holds promise in the green production of alternative fuels and valuable chemicals. Seeking alternative, cost-effective, stable, and possibly reusable catalysts represents a timeless challenge for scientists working in the field. Herein, commercial RuO2 nanostructures were found to be a robust, versatile, and competitive catalyst in H2 photoproduction in several conditions. We employed it in a classic three-component system and compared its activities with those of the widely used platinum nanoparticle catalyst. We observed a hydrogen evolution rate of 0.137 mol h-1 g-1 and an apparent quantum efficiency (AQE) of 6.8% in water using EDTA as an electron donor. Moreover, the favorable employment of l-cysteine as the electron source opens possibilities precluded to other noble metal catalyst. The versatility of the system has also been demonstrated in organic media with impressive H2 production in acetonitrile. The robustness has been proved by the recovery of the catalyst by centrifugation and reusage alternatively in different media.

RuO2 Nanostructure as an Efficient and Versatile Catalyst for H2 Photosynthesis

Gradone A.;Morandi V.;
2023

Abstract

Photocatalytic H2 generation holds promise in the green production of alternative fuels and valuable chemicals. Seeking alternative, cost-effective, stable, and possibly reusable catalysts represents a timeless challenge for scientists working in the field. Herein, commercial RuO2 nanostructures were found to be a robust, versatile, and competitive catalyst in H2 photoproduction in several conditions. We employed it in a classic three-component system and compared its activities with those of the widely used platinum nanoparticle catalyst. We observed a hydrogen evolution rate of 0.137 mol h-1 g-1 and an apparent quantum efficiency (AQE) of 6.8% in water using EDTA as an electron donor. Moreover, the favorable employment of l-cysteine as the electron source opens possibilities precluded to other noble metal catalyst. The versatility of the system has also been demonstrated in organic media with impressive H2 production in acetonitrile. The robustness has been proved by the recovery of the catalyst by centrifugation and reusage alternatively in different media.
2023
Istituto per la Microelettronica e Microsistemi - IMM
catalyst recycling
commercial RuO2
H2
photogeneration in organic solvent
thiol electron−donor
three-component system
File in questo prodotto:
File Dimensione Formato  
bianco-et-al-2023-ruo2-nanostructure-as-an-efficient-and-versatile-catalyst-for-h2-photosynthesis.pdf

accesso aperto

Tipologia: Versione Editoriale (PDF)
Licenza: Creative commons
Dimensione 3.05 MB
Formato Adobe PDF
3.05 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/519555
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 2
  • ???jsp.display-item.citation.isi??? ND
social impact