Self-assembly of trans-{EuI2} nodes and ditopic ligands leads to isoreticular 2D frameworks featuring a rare, non-kagome Archimedean tessellation. The topology and intra-layer Eu(ii)-Eu(ii) antiferromagnetic interactions provide the prerequisites for geometrical spin frustration, which, due to the spin state degeneracy, is key for novel phenomena such as enhanced magnetic refrigeration.
Towards frustration in Eu(ii) Archimedean tessellations
Lorusso, Giulia;
2023
Abstract
Self-assembly of trans-{EuI2} nodes and ditopic ligands leads to isoreticular 2D frameworks featuring a rare, non-kagome Archimedean tessellation. The topology and intra-layer Eu(ii)-Eu(ii) antiferromagnetic interactions provide the prerequisites for geometrical spin frustration, which, due to the spin state degeneracy, is key for novel phenomena such as enhanced magnetic refrigeration.File in questo prodotto:
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a50_2022, Chem Comm Towards frustration in Eu(II) Archimedean tessellations_D2CC06224K.pdf
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