Enhancement of alkaline water electrolysis requires the development of anion exchange membranes (AEMs) combining high permselectivity with a low resistance to ion transport and stability during prolonged contact with a concentrated alkaline solution. We now report that CytroCell@PIL, a mixed matrix membrane obtained by a synergic combination of CytroCell micronized citrus cellulose mixed at a 1 wt% load with a polymerizable ionic liquid (triethyl(4-vinylbenzyl)phosphonium tetrafluoroborate), shows vastly enhanced chemical and physical stability along with promising ionic conductivity. These findings establish the proof of concept toward the development of technical and economically viable large-area AEMs using polymeric membranes chemically and physically stabilized by CytroCell sustainably sourced via cavitation of industrial citrus processing waste conducted in water only.
CytroCell@PIL: A New Citrus Nanocellulose‐Polymeric Ionic Liquid Composite for Enhanced Anion Exchange Membranes
Enrica Fontananova
;Rosaria Ciriminna;Daria Talarico;Francesco Galiano;Alberto Figoli;Gianluca Di Profio;Giuseppe Angellotti;Giovanna Li Petri;Francesco Meneguzzo;Mario Pagliaro
2025
Abstract
Enhancement of alkaline water electrolysis requires the development of anion exchange membranes (AEMs) combining high permselectivity with a low resistance to ion transport and stability during prolonged contact with a concentrated alkaline solution. We now report that CytroCell@PIL, a mixed matrix membrane obtained by a synergic combination of CytroCell micronized citrus cellulose mixed at a 1 wt% load with a polymerizable ionic liquid (triethyl(4-vinylbenzyl)phosphonium tetrafluoroborate), shows vastly enhanced chemical and physical stability along with promising ionic conductivity. These findings establish the proof of concept toward the development of technical and economically viable large-area AEMs using polymeric membranes chemically and physically stabilized by CytroCell sustainably sourced via cavitation of industrial citrus processing waste conducted in water only.| File | Dimensione | Formato | |
|---|---|---|---|
|
CytroCell PIL A New Citrus.pdf
accesso aperto
Descrizione: CytroCell@PIL: A New Citrus Nanocellulose-Polymeric Ionic Liquid Composite for Enhanced Anion Exchange Membranes
Tipologia:
Versione Editoriale (PDF)
Licenza:
Creative commons
Dimensione
2.06 MB
Formato
Adobe PDF
|
2.06 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.


