Enhancement of alkaline water electrolysis requires the development of anion exchange membranes (AEMs) combining high permselectivity with a low resistance to ion transport and stability during prolonged contact with a concentrated alkaline solution. We now report that CytroCell@PIL, a mixed matrix membrane obtained by a synergic combination of CytroCell micronized citrus cellulose mixed at a 1 wt% load with a polymerizable ionic liquid (triethyl(4-vinylbenzyl)phosphonium tetrafluoroborate), shows vastly enhanced chemical and physical stability along with promising ionic conductivity. These findings establish the proof of concept toward the development of technical and economically viable large-area AEMs using polymeric membranes chemically and physically stabilized by CytroCell sustainably sourced via cavitation of industrial citrus processing waste conducted in water only.

CytroCell@PIL: A New Citrus Nanocellulose‐Polymeric Ionic Liquid Composite for Enhanced Anion Exchange Membranes

Enrica Fontananova
;
Rosaria Ciriminna;Daria Talarico;Francesco Galiano;Alberto Figoli;Gianluca Di Profio;Giuseppe Angellotti;Giovanna Li Petri;Francesco Meneguzzo;Mario Pagliaro
2025

Abstract

Enhancement of alkaline water electrolysis requires the development of anion exchange membranes (AEMs) combining high permselectivity with a low resistance to ion transport and stability during prolonged contact with a concentrated alkaline solution. We now report that CytroCell@PIL, a mixed matrix membrane obtained by a synergic combination of CytroCell micronized citrus cellulose mixed at a 1 wt% load with a polymerizable ionic liquid (triethyl(4-vinylbenzyl)phosphonium tetrafluoroborate), shows vastly enhanced chemical and physical stability along with promising ionic conductivity. These findings establish the proof of concept toward the development of technical and economically viable large-area AEMs using polymeric membranes chemically and physically stabilized by CytroCell sustainably sourced via cavitation of industrial citrus processing waste conducted in water only.
2025
Istituto per lo Studio dei Materiali Nanostrutturati - ISMN - Sede Secondaria Palermo
Istituto per la Tecnologia delle Membrane - ITM
Istituto per la BioEconomia - IBE
alkaline water electrolysis
anion exchange membrane
CytroCell
green hydrogen
nanocellulose
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Descrizione: CytroCell@PIL: A New Citrus Nanocellulose-Polymeric Ionic Liquid Composite for Enhanced Anion Exchange Membranes
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/555343
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