This study evaluates the performance and durability of various Aquivion® membranes for PEM electrolysis, focusing on different configurations: bare cast polymers, polymers with radical scavengers and reinforced ones. Membrane-electrode assemblies (MEAs) were produced and tested for hydrogen production by means of polarization curves, electrochemical impedance spectroscopy (EIS) and long-term durability tests. Microscopic and physico-chermical analyses (TEM, SEM, optical microscopy, XRD, XRF,) were used to understand the membrane and ionomer structure and its impact on performance. The goal was to identify optimal membrane strategies for enhancing PEM water electrolysis efficiency and stability in green hydrogen production.

Enhanced PEM Water Electrolysis with Low Equivalent Weight Aquivion® Membranes

Fausta Giacobello
;
Stefania Siracusano;Maria Aurora Mancuso;Veronica Ciccio;Alessandra Muscolino;Antonino Arico
2025

Abstract

This study evaluates the performance and durability of various Aquivion® membranes for PEM electrolysis, focusing on different configurations: bare cast polymers, polymers with radical scavengers and reinforced ones. Membrane-electrode assemblies (MEAs) were produced and tested for hydrogen production by means of polarization curves, electrochemical impedance spectroscopy (EIS) and long-term durability tests. Microscopic and physico-chermical analyses (TEM, SEM, optical microscopy, XRD, XRF,) were used to understand the membrane and ionomer structure and its impact on performance. The goal was to identify optimal membrane strategies for enhancing PEM water electrolysis efficiency and stability in green hydrogen production.
2025
Istituto di Tecnologie Avanzate per l'Energia - ITAE
Water electrolysis, Hydrogen, proton exchange membrane
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/558425
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