Anion exchange membrane water electrolysis (AEMWE) has emerged as a promising technology for green hydrogen production, combining the advantages of both traditional alkaline and proton exchange membrane (PEM) electrolysis systems. It allows for the use of cost-effective, earth-abundant catalysts similar to alkaline systems, while also offering higher current densities and more flexible operational control, similar to PEM electrolyzers. This distinctive combination makes AEMWE a highly efficient and cost-effective solution for large-scale hydrogen production. Catalysts play a crucial role in the efficiency of electrolysis systems, particularly for large-scale green hydrogen production. Precious metal catalysts, while highly effective, are expensive and scarce, which limits their use in largescale applications. In contrast, transition metal catalysts offer an economical and stable alternative, especially in alkaline water electrolysis processes. However, the overall efficiency of these systems is heavily influenced by the kinetics of the oxygen evolution reaction (OER) at the anode. OER is a slow reaction that requires high overpotentials, meaning efficient electrocatalysts are essential to accelerate the process. To address this challenge, non-precious metal catalysts, particularly mixed transition metal oxides such as Ni, Co, Fe, and Mn with spinel or perovskite structures, have shown great promise. These materials provide an effective solution for improving OER performance without the reliance on precious metals. In this presentation, we will focus on the integration of these catalysts into membrane electrode assemblies (MEAs) for enhanced efficiency and cost-effectiveness in AEMWE systems.

Progress in AEM Water Electrolysis: Novel Component Development and MEA Integration

V. Baglio
;
G. Bucca;M. Bottari;C. Lo Vecchio;A. Patti;I. Gatto
2025

Abstract

Anion exchange membrane water electrolysis (AEMWE) has emerged as a promising technology for green hydrogen production, combining the advantages of both traditional alkaline and proton exchange membrane (PEM) electrolysis systems. It allows for the use of cost-effective, earth-abundant catalysts similar to alkaline systems, while also offering higher current densities and more flexible operational control, similar to PEM electrolyzers. This distinctive combination makes AEMWE a highly efficient and cost-effective solution for large-scale hydrogen production. Catalysts play a crucial role in the efficiency of electrolysis systems, particularly for large-scale green hydrogen production. Precious metal catalysts, while highly effective, are expensive and scarce, which limits their use in largescale applications. In contrast, transition metal catalysts offer an economical and stable alternative, especially in alkaline water electrolysis processes. However, the overall efficiency of these systems is heavily influenced by the kinetics of the oxygen evolution reaction (OER) at the anode. OER is a slow reaction that requires high overpotentials, meaning efficient electrocatalysts are essential to accelerate the process. To address this challenge, non-precious metal catalysts, particularly mixed transition metal oxides such as Ni, Co, Fe, and Mn with spinel or perovskite structures, have shown great promise. These materials provide an effective solution for improving OER performance without the reliance on precious metals. In this presentation, we will focus on the integration of these catalysts into membrane electrode assemblies (MEAs) for enhanced efficiency and cost-effectiveness in AEMWE systems.
2025
Istituto di Tecnologie Avanzate per l'Energia - ITAE
Anion exchange membrane water electrolyzers
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/558505
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