Benzyl 2,4-dichlorophenyl sulfoxide was synthesized both in racemic and in an enantiopure form. This enantiopure sulfoxide is a further successful confirmation of our straightforward protocol to yield easily chiral aryl benzyl sulfoxides. We solved also the crystal structure of racemic benzyl 2,4-dichlorophenyl sulfoxide with a single crystal X-ray diffraction experiment. The main interactions building up the crystal structure were recognized and compared with other similar sulfoxides.

Benzyl 2,4-dichlorophenyl sulfoxide

Cardellicchio, Cosimo
2025

Abstract

Benzyl 2,4-dichlorophenyl sulfoxide was synthesized both in racemic and in an enantiopure form. This enantiopure sulfoxide is a further successful confirmation of our straightforward protocol to yield easily chiral aryl benzyl sulfoxides. We solved also the crystal structure of racemic benzyl 2,4-dichlorophenyl sulfoxide with a single crystal X-ray diffraction experiment. The main interactions building up the crystal structure were recognized and compared with other similar sulfoxides.
2025
Istituto di Chimica dei Composti Organo Metallici - ICCOM - Sede Secondaria Bari
weak interactions
crystal structure
enantioselective oxidation
sulfoxide
titanium complex
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/561941
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