Many paintings from the 19th century have exhibited signs of fading and discoloration, often linked to cadmium yellow, a pigment widely used by artists during that time. In this work, we develop a mathematical model of the cadmium sulfide photo catalytic reaction responsible for these damages. By employing nonlo cal integral operators, we capture the interplay between chemical processes and environmental factors, offering a detailed representation of the degradation mechanisms. Furthermore, we present a second order positivity-preserving numerical method designed to accurately simulate the phenomenon and ensure reliable predictions across different scenarios, along with a comprehensive sensitivity analysis of the model.

AN INTEGRO-DIFFERENTIAL MODEL OF CADMIUM YELLOW PHOTODEGRADATION

Ceseri M.;Natalini R.;Pezzella M.
2025

Abstract

Many paintings from the 19th century have exhibited signs of fading and discoloration, often linked to cadmium yellow, a pigment widely used by artists during that time. In this work, we develop a mathematical model of the cadmium sulfide photo catalytic reaction responsible for these damages. By employing nonlo cal integral operators, we capture the interplay between chemical processes and environmental factors, offering a detailed representation of the degradation mechanisms. Furthermore, we present a second order positivity-preserving numerical method designed to accurately simulate the phenomenon and ensure reliable predictions across different scenarios, along with a comprehensive sensitivity analysis of the model.
2025
Istituto Applicazioni del Calcolo ''Mauro Picone''
integro-differential models
photochemical reactions
cultural heritage
positivity-preserving numerical methods
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/562648
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