Enhanced thermoelectricity in nanowires with inhomogeneous helical states

Semiconductor nanowires (NWs) with strong Rashba spin-orbit coupling (RSOC), when exposed to a suitably applied Zeeman field, exhibit one-dimensional helical channels with a spin orientation locked to the propagation direction within the magnetic energy gap. Here, by adopting a scattering-matrix approach applied to a tight-binding model of the NW, we demonstrate that the thermoelectric (TE) properties can be widely controlled by tuning the misalignment angle ϕ between the spin-orbit directions of two NW segments. In particular, when the RSOC vectors are antiparallel (Dirac-paradox configuration), we predict a significant violation of the Wiedemann-Franz law, and a strong enhancement of the Seebeck coefficient and the ZT figure of merit. We also show that the Zeeman gap determines the optimal energy window for doping and temperatures. These results suggest that controlling the spin-orbit field direction, which can be achieved with suitably applied wrap gates, is a promising alternative for tuning and optimizing the TE response in quantum-coherent semiconducting NW devices.