This paper presents a theoretical investigation of the cross sections for dissociative electron attachment and dissociative excitation processes in vibrationally excited CH radicals induced by electron impact. Resonant electron-CH collisions are analyzed using the ab initio R-matrix method, while nuclear dynamics are explored within the local complex potential framework. A comprehensive set of vibrationally resolved cross sections and rate coefficients is provided for both the ground and first excited electronic states of the CH molecule. These findings contribute to a better understanding of the kinetics of nonequilibrium systems containing CH molecules with applications in plasma technologies for CO2 reduction, combustion processes, and various astrophysical contexts.
Electron-impact cross sections for dissociation processes of the vibrationally excited CH radical
V. Laporta
Ultimo
Conceptualization
2025
Abstract
This paper presents a theoretical investigation of the cross sections for dissociative electron attachment and dissociative excitation processes in vibrationally excited CH radicals induced by electron impact. Resonant electron-CH collisions are analyzed using the ab initio R-matrix method, while nuclear dynamics are explored within the local complex potential framework. A comprehensive set of vibrationally resolved cross sections and rate coefficients is provided for both the ground and first excited electronic states of the CH molecule. These findings contribute to a better understanding of the kinetics of nonequilibrium systems containing CH molecules with applications in plasma technologies for CO2 reduction, combustion processes, and various astrophysical contexts.| File | Dimensione | Formato | |
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PRA_CH_diss.pdf
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