Iron(III)-based single-molecule magnets have been covalently grafted on Au(111) in one step using 1,2-dithiolan-3-yl side groups. Reaction with the substrate quantitatively affords a monolayer of electronically intact clusters doubly linked to the surface via AuS bonds, as demonstrated by a combination of STM, XAS/XMCD and XPS studies.
One-step covalent grafting of Fe4 single-molecule magnet monolayers on gold
Armelao L;
2010
Abstract
Iron(III)-based single-molecule magnets have been covalently grafted on Au(111) in one step using 1,2-dithiolan-3-yl side groups. Reaction with the substrate quantitatively affords a monolayer of electronically intact clusters doubly linked to the surface via AuS bonds, as demonstrated by a combination of STM, XAS/XMCD and XPS studies.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
