Kinetic peculiarities of cis and trans methyl oleate formation in the course of methyl linoleate hydrogenation over Pd/MgO were, studied. Liquid phase hydrogenation was carried out in temperature range of 303-323 K and under hydrogen pressure within 1-10 bar. Gas-liquid chromatography, IR and C-13 NMR techniques were employed to characterize the reaction products. Effects of hydrogen pressure. and re-action temperature on cis and trans methyl oleate. formation were studied. The General kinetic scheme and reaction mechanism of methyl linoleate hydrogenation and cis-trans methyl oleate isomerization have been proposed.
Kinetic peculiarities of cis/trans methyl oleate formation during hydrogenation of methyl linoleate over Pd/MgO
Psaro R;Dal Santo V;
2005
Abstract
Kinetic peculiarities of cis and trans methyl oleate formation in the course of methyl linoleate hydrogenation over Pd/MgO were, studied. Liquid phase hydrogenation was carried out in temperature range of 303-323 K and under hydrogen pressure within 1-10 bar. Gas-liquid chromatography, IR and C-13 NMR techniques were employed to characterize the reaction products. Effects of hydrogen pressure. and re-action temperature on cis and trans methyl oleate. formation were studied. The General kinetic scheme and reaction mechanism of methyl linoleate hydrogenation and cis-trans methyl oleate isomerization have been proposed.| File | Dimensione | Formato | |
|---|---|---|---|
|
prod_47822-doc_29581.pdf
solo utenti autorizzati
Descrizione: Kinetic peculiarities of cis/trans methyl oleate formation during hydrogenation of methyl linoleate over Pd/Mg0
Dimensione
551.37 kB
Formato
Adobe PDF
|
551.37 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
