The synthesis and characterization of two bifunctional composite materials based on synthetic saponite clays is here presented. These materials were prepared by intercalation of a Ti-containing aminopropylisobutylPOSS (Ti-NH2POSS) in synthetic saponite samples containing interlayer sodium (Na-SAP) and protons (H-SAP). Hybrid inorganic/organic composite materials, Ti-NHM-1 and Ti-NHM-2, were obtained upon ion exchange. Structural, spectroscopic and thermal properties of both hybrid materials were investigated in detail along with their catalytic activity in cyclohexene oxidation.

Organic-Inorganic Hybrid Saponites Obtained by Intercalation of Titano-Silsesquioxane

Guidotti M;Sordelli L;
2011

Abstract

The synthesis and characterization of two bifunctional composite materials based on synthetic saponite clays is here presented. These materials were prepared by intercalation of a Ti-containing aminopropylisobutylPOSS (Ti-NH2POSS) in synthetic saponite samples containing interlayer sodium (Na-SAP) and protons (H-SAP). Hybrid inorganic/organic composite materials, Ti-NHM-1 and Ti-NHM-2, were obtained upon ion exchange. Structural, spectroscopic and thermal properties of both hybrid materials were investigated in detail along with their catalytic activity in cyclohexene oxidation.
2011
Istituto di Scienze e Tecnologie Molecolari - ISTM - Sede Milano
Silsesquioxanes
POSS
titanium
sapopnite
hybrid materials
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/75650
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact