We have performed small angle neutron scattering experiments on the binary fluid mixture n-C6 H14 +n-C8 F18 imbibed inside porous Vycor glass in the thermodynamic region corresponding to the bulk critical one. The resulting structure can be represented as the sum of a temperature dependent Lorentzian term and a term describing the interference between the porous matrix, a shell part richer in one component coating the glass surface, and a core part richer in the other component. We observe critical fluctuations extending over distances markedly larger than the mean pore size.
Critical fluctuations of a binary fluid mixture confined in a porous medium
F Formisano;
2000
Abstract
We have performed small angle neutron scattering experiments on the binary fluid mixture n-C6 H14 +n-C8 F18 imbibed inside porous Vycor glass in the thermodynamic region corresponding to the bulk critical one. The resulting structure can be represented as the sum of a temperature dependent Lorentzian term and a term describing the interference between the porous matrix, a shell part richer in one component coating the glass surface, and a core part richer in the other component. We observe critical fluctuations extending over distances markedly larger than the mean pore size.File in questo prodotto:
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