The14N and35Cl nuclear quadrupole coupling constants of the14N32S35Cl isotopic species of thiazyl chloride have been determined from an analysis of the hyperfine structure of six? a and? b transitions in the microwave spectrum as (in MHz) ?aa (35CL) = -39.00(3), ?bb (35CL) = 23.84(4), ?aa (14N) = -1.42(6), ?bb (14N) = -4.16(6).
Le costanti di accoppiamento quadrupolare di14N e35Cl della specie isotopica14N32S35Cl del tiazil cloruro sono state determinate attraverso l'analisi della struttura iperfine di sei transizioni di tipo? a e? b dello spettro a microonde. Si sono ottenuti i seguenti valori (in MHz): ?aa (35CL) = -39.00(3), ?bb (35CL) = 23.84(4), ?aa (14N) = -1.42(6), ?bb (14N) = -4.16(6).
14^N and 15^Cl nuclear-quadrupole coupling constants in thiazyl chloride from microvawe spectroscopy and ab initio molecular orbital computations
A Degli Esposti;
1984
Abstract
The14N and35Cl nuclear quadrupole coupling constants of the14N32S35Cl isotopic species of thiazyl chloride have been determined from an analysis of the hyperfine structure of six? a and? b transitions in the microwave spectrum as (in MHz) ?aa (35CL) = -39.00(3), ?bb (35CL) = 23.84(4), ?aa (14N) = -1.42(6), ?bb (14N) = -4.16(6).I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
