Free radical polymerization of both ?-(trifluoromethyl)acrylic acid (TFMAA) and its methyl ester MTFMA is shown to be possible in the presence of bis(4-tert-butylcyclohexyl) peroxycarbonate (Percadox) as initiator and dioxane or THF as solvent. Also it is shown that copolymers of TFMAA with alfa-olefins (1-decene, 2-methyl-1-hexene) and of methyl alfa-(trifluoromethyl)acrylate (MTFMA) with vinyl ethers (butyl, 2-ethylhexyl, and menthyl vinyl ether) can be simply obtained with AIBN as initiator; these copolymers have a predominantly alternating structure.
Synthesis of new polymers containig alfa -(trifluoromethyl)-acrylate units
E Passaglia;
1995
Abstract
Free radical polymerization of both ?-(trifluoromethyl)acrylic acid (TFMAA) and its methyl ester MTFMA is shown to be possible in the presence of bis(4-tert-butylcyclohexyl) peroxycarbonate (Percadox) as initiator and dioxane or THF as solvent. Also it is shown that copolymers of TFMAA with alfa-olefins (1-decene, 2-methyl-1-hexene) and of methyl alfa-(trifluoromethyl)acrylate (MTFMA) with vinyl ethers (butyl, 2-ethylhexyl, and menthyl vinyl ether) can be simply obtained with AIBN as initiator; these copolymers have a predominantly alternating structure.File in questo prodotto:
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