CNR Institutional Research Information System

Adamantane (1) can be converted directly into adamantan-1,3,5-triol (5) and into adamantan-1,3,5,7-tetraol (6) under remarkably mild conditions by employing an excess of isolated methyl(trifluoromethyl)dioxirane (3a) in solution. This new dioxirane species was found to be over 7,000-fold more reactive than dimethyldioxirane (3b) in performing adamantane hydroxylations

Oxidations by methyl(trifluoromethyl)dioxirane. 3. Selective polyoxyfunctionalization of adamantane

Fusco C;
1990

Abstract

Adamantane (1) can be converted directly into adamantan-1,3,5-triol (5) and into adamantan-1,3,5,7-tetraol (6) under remarkably mild conditions by employing an excess of isolated methyl(trifluoromethyl)dioxirane (3a) in solution. This new dioxirane species was found to be over 7,000-fold more reactive than dimethyldioxirane (3b) in performing adamantane hydroxylations
1990
Istituto di Chimica dei Composti OrganoMetallici - ICCOM -
Inglese
WOS:A1990DH36700033
31
3067
3070
4
http://biblioproxy.cnr.it:2065/10.1016/S0040-4039(00)89027-9
Sì, ma tipo non specificato
Adamantane could be converted directly into adamantane-1,3,5-triol (5) or into adamantane-1,3,5,7-tetraol (6) under mild conditions by employing an appropriate excess of the title dioxirane 3a.
1
info:eu-repo/semantics/article
262
Mello, R.; Cassidei, L.; Fiorentino, M.; Fusco, C.; Curci, R.
01 Contributo su Rivista::01.01 Articolo in rivista
none
01.01 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/118549
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