C- and O-alkylation of cyclic and linear ketones is carried out by electrochemical reduction of primary, secondary and tertiary alkyl bromides in DMF in the presence of the above-mentioned ketones. A coupling mechanism involving carbanions (C-alkylation) and oxanions (O-alkylation) is proposed
ELECTROCHEMICAL ALKYLATION OF CYCLIC AND LINEAR KETONES
Curulli Antonella;
1987
Abstract
C- and O-alkylation of cyclic and linear ketones is carried out by electrochemical reduction of primary, secondary and tertiary alkyl bromides in DMF in the presence of the above-mentioned ketones. A coupling mechanism involving carbanions (C-alkylation) and oxanions (O-alkylation) is proposedFile in questo prodotto:
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