We have measured the depolarized-light-scattering spectrum of normal H2 at T=297 K as a function of the density between ?=17.8 and ?=129 amagat up to the frequency ?=865 cm-1. The spectrum between 6 and 240 cm-1 is dominated by the ''translational'' depolarized interaction-induced part from which the two-body spectrum and the three-body correlation spectrum have been extracted and compared with the theoretical predictions obtained with the dipole-induced-dipole polarizability model and an isotropic pair-interaction potential. We have also measured the spectrum in the wings of the rotational transition S(0),S(1),S(2) between 240 and 865 cm-1 and demonstrated, for the first time, its quadratic behavior versus density in the above-mentioned density range. This portion of the spectrum is attributed mostly to pure collisional broadening.
Depolarized-light-scattering spectrum of normal gaseous hydrogen at low density and a temperature of 297 K
Bafile U.;Ulivi L.;Zoppi M.;
1988
Abstract
We have measured the depolarized-light-scattering spectrum of normal H2 at T=297 K as a function of the density between ?=17.8 and ?=129 amagat up to the frequency ?=865 cm-1. The spectrum between 6 and 240 cm-1 is dominated by the ''translational'' depolarized interaction-induced part from which the two-body spectrum and the three-body correlation spectrum have been extracted and compared with the theoretical predictions obtained with the dipole-induced-dipole polarizability model and an isotropic pair-interaction potential. We have also measured the spectrum in the wings of the rotational transition S(0),S(1),S(2) between 240 and 865 cm-1 and demonstrated, for the first time, its quadratic behavior versus density in the above-mentioned density range. This portion of the spectrum is attributed mostly to pure collisional broadening.File | Dimensione | Formato | |
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Descrizione: Depolarized-light-scattering spectrum of normal gaseous hydrogen at low density and a temperature of 297 K
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