By employing either dimethyldioxirane or its trifluoromethyl analog, the direct, high-yield conversion of one cyclic and three open chain optically sec,sec-1,2-diols to the corresponding alpha-hydroxy ketones in high optical yield has been achieved

Selective oxidation of optically active sec,sec-1,2-diols by dioxiranes. A practical method for the synthesis of homochiral alpha-hydroxy ketones in high optical purity

Fusco C;
1993

Abstract

By employing either dimethyldioxirane or its trifluoromethyl analog, the direct, high-yield conversion of one cyclic and three open chain optically sec,sec-1,2-diols to the corresponding alpha-hydroxy ketones in high optical yield has been achieved
1993
Istituto di Chimica dei Composti OrganoMetallici - ICCOM -
Catalyzed asymmetric dihydroxylation
enantioselective synthesis
methyl(trifluoromethyl)dioxirane
alcohols
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/126868
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? 51
social impact