1,2-Diphenyl- and 1-phenyl-2-(2-pyridyl)-1,2-disodiumethane efficiently dehalogenate vic-dibromoderivatives, affording the corresponding alkenes. The reaction proceeds rapidly, under mild conditions, and is tolerant of a variety of functional groups (alcohol, carboxylic acid, ester, amide). This procedure was successfully extended to similar vic-disubstituted compounds.
Reducing properties of 1,2 - diaryl - 1,2 - disodiumethanes
Azara E
2006
Abstract
1,2-Diphenyl- and 1-phenyl-2-(2-pyridyl)-1,2-disodiumethane efficiently dehalogenate vic-dibromoderivatives, affording the corresponding alkenes. The reaction proceeds rapidly, under mild conditions, and is tolerant of a variety of functional groups (alcohol, carboxylic acid, ester, amide). This procedure was successfully extended to similar vic-disubstituted compounds.File in questo prodotto:
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