We report a detailed experimental characterization of the infrared absorption properties of the high pressure, red phase of oxygen. Spectra are measured in the far infrared, down to 100 cm-1, in the fundamental vibration and in the overtone regions up to 63 GPa. A new, strong peak is observed at about 300 cm-1. Samples less than 0.5 um thick were produced to measure the strong vibron mode avoiding saturation. We find that the diatomic oxygen molecule is not a good basis to describe the vibrational spectrum of the epsilon phase. The spectra can be interpreted in a straightforward way on the basis of an association among the oxygen molecules leading to the formation of O4 units.
The epsilon phase of solid oxygen: evidence of an O4 molecule lattice.
Federico A. Gorelli;Lorenzo Ulivi;Mario Santoro;Roberto Bini
1999
Abstract
We report a detailed experimental characterization of the infrared absorption properties of the high pressure, red phase of oxygen. Spectra are measured in the far infrared, down to 100 cm-1, in the fundamental vibration and in the overtone regions up to 63 GPa. A new, strong peak is observed at about 300 cm-1. Samples less than 0.5 um thick were produced to measure the strong vibron mode avoiding saturation. We find that the diatomic oxygen molecule is not a good basis to describe the vibrational spectrum of the epsilon phase. The spectra can be interpreted in a straightforward way on the basis of an association among the oxygen molecules leading to the formation of O4 units.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.