The structural properties of a mixture of ethylammonium nitrate (EAN), a protic ionic liquid, and lithium nitrate are explored using X-ray diffraction and reverse Monte Carlo simulation. The system is characterised by the amphiphilically driven polar-apolar domains segregation that is peculiar of EAN, whilst the lithium ions distribute in the charged domains where they undergo a further level of self-segregation, prompting for a new ion solvation mechanism in amphiphilically nanostructured ionic liquids. © 2014 Elsevier B.V. All rights reserved.
How does lithium nitrate dissolve in a protic ionic liquid?
Triolo A
2014
Abstract
The structural properties of a mixture of ethylammonium nitrate (EAN), a protic ionic liquid, and lithium nitrate are explored using X-ray diffraction and reverse Monte Carlo simulation. The system is characterised by the amphiphilically driven polar-apolar domains segregation that is peculiar of EAN, whilst the lithium ions distribute in the charged domains where they undergo a further level of self-segregation, prompting for a new ion solvation mechanism in amphiphilically nanostructured ionic liquids. © 2014 Elsevier B.V. All rights reserved.File in questo prodotto:
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