Two novel chiral porphyrin (5) and (7), with two and four alditolyl chains attached at the bridging methane carbons, have been synthesized via, respectively, coupling of the dipyrril unit (3) with p-fluorobenzaldehyde (4) and BF3-catalyzed condensation between pyrrole and 2,3-O-isopropylidene-D-glyceraldehyde (6).
Synthesis of Porphyrin C-Glycoconjugates
Rassu G;Spanu P
1992
Abstract
Two novel chiral porphyrin (5) and (7), with two and four alditolyl chains attached at the bridging methane carbons, have been synthesized via, respectively, coupling of the dipyrril unit (3) with p-fluorobenzaldehyde (4) and BF3-catalyzed condensation between pyrrole and 2,3-O-isopropylidene-D-glyceraldehyde (6).File in questo prodotto:
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