?-Fe2O3/CuO nanosystems were synthesised by using a two-step plasma-assisted strategy. ?-Fe2O3 nanostructures (host) were initially deposited by plasma assisted-chemical vapour deposition (PA-CVD) on indium tin oxide (ITO) substrates. Subsequently, CuO nanoparticles (NPs, guest) were over-deposited on host matrices by means of radio frequency (RF) sputtering under mild conditions. The combined use of structural, morphological and chemical analyses evidenced the formation of pure and homogeneous ?-Fe2O3/CuO systems possessing a high dispersion of CuO NPs in/on ?-Fe2O3hosts. The target nanomaterials were characterized by an intimate contact between the two oxides, with CuO NP size and tuneable content as a function of sputtering time. These features, along with the tailored nano-organization, make the present ?-Fe2O3/CuO nanosystems attractive candidates for diverse technological applications involving solar light harvesting.

A plasma-assisted approach for the controlled dispersion of CuO aggregates into beta iron(iii) oxide matrices

BARRECA, DAVIDE
2014

Abstract

?-Fe2O3/CuO nanosystems were synthesised by using a two-step plasma-assisted strategy. ?-Fe2O3 nanostructures (host) were initially deposited by plasma assisted-chemical vapour deposition (PA-CVD) on indium tin oxide (ITO) substrates. Subsequently, CuO nanoparticles (NPs, guest) were over-deposited on host matrices by means of radio frequency (RF) sputtering under mild conditions. The combined use of structural, morphological and chemical analyses evidenced the formation of pure and homogeneous ?-Fe2O3/CuO systems possessing a high dispersion of CuO NPs in/on ?-Fe2O3hosts. The target nanomaterials were characterized by an intimate contact between the two oxides, with CuO NP size and tuneable content as a function of sputtering time. These features, along with the tailored nano-organization, make the present ?-Fe2O3/CuO nanosystems attractive candidates for diverse technological applications involving solar light harvesting.
2014
Istituto di Chimica della Materia Condensata e di Tecnologie per l'Energia - ICMATE
Inglese
16
37
8710
8716
7
http://pubs.rsc.org/en/Content/ArticleLanding/2014/CE/C4CE01274G#!divAbstract
Sì, ma tipo non specificato
Fe2O3
CuO
nanosystems
PE-CVD
sputtering
Autori stranieri; invited paper
1
info:eu-repo/semantics/article
262
Barreca, Davide
01 Contributo su Rivista::01.01 Articolo in rivista
none
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/283701
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