The linear and non-linear thermoelectric properties of molecular junctions are theoretically studied close to room temperature within a model including electron-electron and electron-vibration interactions on the molecule. A non-equilibrium adiabatic approach is devised to include a strong Coulomb repulsion and applied to the self-consistent calculation of electron and phonon transport properties of massive molecules, such as fullerenes, within the Coulomb blockade regime. We show that the phonon thermal conductance is quite sensitive to strong electron-electron interactions within the intermediate electron-vibration coupling regime. Furthermore, the electron-vibration interaction enhances both phonon and electron thermal conductance, and it reduces not only the charge conductance, but also the thermopower. The effect of the strong electron-electron interactions provides a peculiar double-peak structure to the thermopower versus charge conductance curve. Finally, within the regime of weak to intermediate electron-vibration and vibration-lead phonon coupling, the peak values of the thermoelectric figure of merit are slightly less than unity, and the maximal efficiency of the junction can reach values slightly less than half of the Carnot limit for large temperature differences between the leads.

Interplay between electron-electron and electron-vibration interactions on the thermoelectric properties of molecular junctions

Perroni CA;Ninno D;Cataudella V
2015

Abstract

The linear and non-linear thermoelectric properties of molecular junctions are theoretically studied close to room temperature within a model including electron-electron and electron-vibration interactions on the molecule. A non-equilibrium adiabatic approach is devised to include a strong Coulomb repulsion and applied to the self-consistent calculation of electron and phonon transport properties of massive molecules, such as fullerenes, within the Coulomb blockade regime. We show that the phonon thermal conductance is quite sensitive to strong electron-electron interactions within the intermediate electron-vibration coupling regime. Furthermore, the electron-vibration interaction enhances both phonon and electron thermal conductance, and it reduces not only the charge conductance, but also the thermopower. The effect of the strong electron-electron interactions provides a peculiar double-peak structure to the thermopower versus charge conductance curve. Finally, within the regime of weak to intermediate electron-vibration and vibration-lead phonon coupling, the peak values of the thermoelectric figure of merit are slightly less than unity, and the maximal efficiency of the junction can reach values slightly less than half of the Carnot limit for large temperature differences between the leads.
2015
Istituto Superconduttori, materiali innovativi e dispositivi - SPIN
electron-electron and electron-vibration interactions
Thermoelectric properties
molecular junctions
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/303047
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