We present a new class of thiophene-based oligomers and polymers with widely tunable photo and electroluminescence properties and which offer great potential for many different areas of application. We were able to synthesize materials displaying high solid-state fluorescence efficiency across the entire visible range. Electroactive polymers emitting light in the near IR were obtained by chemical and/or electrochemical polymerization of oligomers of different length. The polymers also displayed electrochromism, i.e. color change when electric current flowed through the material. All compounds were characterized by great thermo and photooxidative stability. With some of these materials efficient electroluminescent devices were fabricated and characterized.

Chemically and thermally stable photo and electroluminescent thiophene-based materials

Barbarella G;Favaretto L;Zambianchi M;Gigli G;
2000

Abstract

We present a new class of thiophene-based oligomers and polymers with widely tunable photo and electroluminescence properties and which offer great potential for many different areas of application. We were able to synthesize materials displaying high solid-state fluorescence efficiency across the entire visible range. Electroactive polymers emitting light in the near IR were obtained by chemical and/or electrochemical polymerization of oligomers of different length. The polymers also displayed electrochromism, i.e. color change when electric current flowed through the material. All compounds were characterized by great thermo and photooxidative stability. With some of these materials efficient electroluminescent devices were fabricated and characterized.
2000
0-8194-3779-4
thiophene
oligomers
polymers
synthesis
electron affinity
photoluminescence
electroluminescence
UV-Vis
near DR
electrochromism
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/310117
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