The absorption and induced circular dichroism (icd) spectra of the alpha-CD:DMABN system in water solution at 20^ C evidenced the presence of 1:1 and 2:1 complexes. The beta-CD:DMABN system was found to be characterized by 1:1 and 2:2 associates. The association constants and the absolute absorption and icd spectra of each species was determined by dynamic Monte Carlo (DMC) calculations including solvation effects and induced circular dichroism calculations.
A spectroscopic and structural characterization of the inclusion complexes of p-dimethylaminobenzonitrile with cyclodextrins
Monti S;Marconi G;Manoli F;
2003
Abstract
The absorption and induced circular dichroism (icd) spectra of the alpha-CD:DMABN system in water solution at 20^ C evidenced the presence of 1:1 and 2:1 complexes. The beta-CD:DMABN system was found to be characterized by 1:1 and 2:2 associates. The association constants and the absolute absorption and icd spectra of each species was determined by dynamic Monte Carlo (DMC) calculations including solvation effects and induced circular dichroism calculations.File in questo prodotto:
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