In recent years, a large interest has been reported on low-dimensional ?-Ga2O3 structures, like nano- wires, nanobelts, nanorods or nanosheets, because of their peculiar and sometimes superior properties. These properties, however, can be strongly affected by the growth procedure, especially if metal growth catalysts are used. In this work we report the successful synthesis of ?-Ga2O3 nanowires/nanobelts using a simple combination of thermal evaporation of a metallic Ga source and controlled oxidation. The same growth procedure has been used to grow nanostructures on different kind of substrates (silicon and alumina), without catalyst as well as with Au or Pt deposited on the substrates, in order to promote the nucleation of nanowires. The morphological, structural and optical properties of the obtained nanos- tructures have been characterized and compared. Different growth distributions on the substrates and possible growth mechanisms have been highlighted, while a strong increase in luminescence intensity has been observed on samples grown with Au and Pt catalysts.

Growth and characterization of beta-Ga2O3 nanowires obtained on not-catalyzed and Au/Pt catalyzed substrates

Calestani Davide;Villani Marco;Lazzarini Laura;Fabbri Filippo;Salviati Giancarlo;Zappettini Andrea
2017

Abstract

In recent years, a large interest has been reported on low-dimensional ?-Ga2O3 structures, like nano- wires, nanobelts, nanorods or nanosheets, because of their peculiar and sometimes superior properties. These properties, however, can be strongly affected by the growth procedure, especially if metal growth catalysts are used. In this work we report the successful synthesis of ?-Ga2O3 nanowires/nanobelts using a simple combination of thermal evaporation of a metallic Ga source and controlled oxidation. The same growth procedure has been used to grow nanostructures on different kind of substrates (silicon and alumina), without catalyst as well as with Au or Pt deposited on the substrates, in order to promote the nucleation of nanowires. The morphological, structural and optical properties of the obtained nanos- tructures have been characterized and compared. Different growth distributions on the substrates and possible growth mechanisms have been highlighted, while a strong increase in luminescence intensity has been observed on samples grown with Au and Pt catalysts.
2017
Istituto dei Materiali per l'Elettronica ed il Magnetismo - IMEM
A1. Nanostructures
A3. Chemical vapor deposition processes
B1. Nanomaterials
B1. Oxides
B2. Semiconducting gallium compounds
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/325102
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