In recent years, a large interest has been reported on low-dimensional ?-Ga2O3 structures, like nano- wires, nanobelts, nanorods or nanosheets, because of their peculiar and sometimes superior properties. These properties, however, can be strongly affected by the growth procedure, especially if metal growth catalysts are used. In this work we report the successful synthesis of ?-Ga2O3 nanowires/nanobelts using a simple combination of thermal evaporation of a metallic Ga source and controlled oxidation. The same growth procedure has been used to grow nanostructures on different kind of substrates (silicon and alumina), without catalyst as well as with Au or Pt deposited on the substrates, in order to promote the nucleation of nanowires. The morphological, structural and optical properties of the obtained nanos- tructures have been characterized and compared. Different growth distributions on the substrates and possible growth mechanisms have been highlighted, while a strong increase in luminescence intensity has been observed on samples grown with Au and Pt catalysts.
Growth and characterization of beta-Ga2 O3 nanowires obtained on not-catalyzed and Au/Pt catalyzed substrates
Calestani Davide;Coppedè Nicola;Villani Marco;Lazzarini Laura;Fabbri Filippo;Salviati Giancarlo;Zappettini Andrea
2017
Abstract
In recent years, a large interest has been reported on low-dimensional ?-Ga2O3 structures, like nano- wires, nanobelts, nanorods or nanosheets, because of their peculiar and sometimes superior properties. These properties, however, can be strongly affected by the growth procedure, especially if metal growth catalysts are used. In this work we report the successful synthesis of ?-Ga2O3 nanowires/nanobelts using a simple combination of thermal evaporation of a metallic Ga source and controlled oxidation. The same growth procedure has been used to grow nanostructures on different kind of substrates (silicon and alumina), without catalyst as well as with Au or Pt deposited on the substrates, in order to promote the nucleation of nanowires. The morphological, structural and optical properties of the obtained nanos- tructures have been characterized and compared. Different growth distributions on the substrates and possible growth mechanisms have been highlighted, while a strong increase in luminescence intensity has been observed on samples grown with Au and Pt catalysts.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.