Archaeometric Study on Roman Painted Terracottas from the Sanctuary of Hercules in Alba Fucens (Abruzzo, Italy)

In a period spanning from the 7th to the 1st century BC, the exterior surfaces of civil and sacred buildings in Italy were mainly decorated with terracottas. The aim of this study is to determine the skills and technological level reached by ancient manufacturers of painted ceramics from the sanctuary of Hercules in the archaeological site of Alba Fucens (Abruzzo, Central Italy). A multi-analytical approach including X-ray Powder Diffraction (XRPD) -Raman and portable X- ray fluorescence (pXRF) was applied to determine the mineralogical composition of terracotta samples and to identify the pigments decorating the ceramics. The studied terracottas were decorated using valuable pigments such as Egyptian blue as well as a palette of colors common in the Roman period from the 3rd to the 1st century BC. The mineralogical composition of the ceramics allows estimating a firing temperature lower than 800 °C. Finally, a local origin of raw materials is suggested by the presence of alluvial and lake deposits outcropping in the Fucino area.