Among the technologies adopted in the building-integrated photovoltaics sector, dye-sensitized solar cells appear very attractive because of unique features like tunable color and good transparency. However, the prospect of their low-cost fabrication is realistic only if reliable and scalable processes under real manufacturing conditions (i.e., pilot line and/or plant factory) are designed, developed, and optimized for large-area, efficient, and stable devices. Herein, a highly reproducible process is shown based on the deposition of different inks by screen-printing technique to realize twenty modules (400 cm2) and one panel (0.2 m2) incorporating an organic sensitizer. Module design considers the resistive losses caused by electron transport, the durability of the device and its aspect ratio (>70%). The module champion efficiency is 5.1% with 35.7% transparency (average visible transmittance), and its stability is determined to be >1000 h according to two International Summit on Organic Photovoltaic Stability (ISOS) protocols (D-2 and L-1). The modules show no structural failures, electrolyte leakage, or other signs of degradation. The consistency of the gap between photo- and counter-electrodes before and after stress is demonstrated. An industrial lamination process to realize a panel with an outdoor efficiency of 2.7% at 60 °C tilt angle is adopted.

Process Engineering of Semitransparent DSSC Modules and Panel Incorporating an Organic Sensitizer

Massimo Calamante;Alessio Dessi';Alessandro Mordini;Lorenzo Zani
;
Aldo Di Carlo
2022

Abstract

Among the technologies adopted in the building-integrated photovoltaics sector, dye-sensitized solar cells appear very attractive because of unique features like tunable color and good transparency. However, the prospect of their low-cost fabrication is realistic only if reliable and scalable processes under real manufacturing conditions (i.e., pilot line and/or plant factory) are designed, developed, and optimized for large-area, efficient, and stable devices. Herein, a highly reproducible process is shown based on the deposition of different inks by screen-printing technique to realize twenty modules (400 cm2) and one panel (0.2 m2) incorporating an organic sensitizer. Module design considers the resistive losses caused by electron transport, the durability of the device and its aspect ratio (>70%). The module champion efficiency is 5.1% with 35.7% transparency (average visible transmittance), and its stability is determined to be >1000 h according to two International Summit on Organic Photovoltaic Stability (ISOS) protocols (D-2 and L-1). The modules show no structural failures, electrolyte leakage, or other signs of degradation. The consistency of the gap between photo- and counter-electrodes before and after stress is demonstrated. An industrial lamination process to realize a panel with an outdoor efficiency of 2.7% at 60 °C tilt angle is adopted.
2022
Istituto di Chimica dei Composti OrganoMetallici - ICCOM -
Istituto di Struttura della Materia - ISM - Sede Roma Tor Vergata
BIPV
dye sensitized solar cells
PV modules
PV panels
semitransparent solar cells
stability studies
File in questo prodotto:
File Dimensione Formato  
prod_467747-doc_184655.pdf

solo utenti autorizzati

Descrizione: Process Engineering of Semitransparent DSSC Modules and Panel Incorporating an Organic Sensitizer
Tipologia: Versione Editoriale (PDF)
Licenza: NON PUBBLICO - Accesso privato/ristretto
Dimensione 3.23 MB
Formato Adobe PDF
3.23 MB Adobe PDF   Visualizza/Apri   Richiedi una copia
solar-rrl-S-22-00479_preprint.pdf

accesso aperto

Descrizione: This is the pre-peer reviewed version of the following article: [L. Vesce, P. Mariani, M. Calamante, A. Dessì, A. Mordini, L. Zani A. Di Carlo, "Process engineering of semi-transparent DSSC modules and panel incorporating an organic sensitizer", Solar RRL 2022, 6, 2200403], which has been published in final form at [https://doi.org/10.1002/solr.202200403]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Tipologia: Documento in Pre-print
Licenza: Altro tipo di licenza
Dimensione 1.29 MB
Formato Adobe PDF
1.29 MB Adobe PDF Visualizza/Apri

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/441505
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 11
  • ???jsp.display-item.citation.isi??? ND
social impact