Time-series crystallization/dissolution experiments were conducted on a natural potassicbasalt seeded with bytownitic plagioclases (Plg) at atmospheric pressure, in air, at 1180-1240 °C and isothermal dwell time up to 20 hours. Plg-seed presence promotes the earlyformation of new-Plg, dampening the clinopyroxene (Cpx) crystallization. New-Plgsgrow at a rate from 10-6 up to 10-8 cm·s-1 as the dwell time increases. Seeds overgrowat similar rate. Cpx crystallizes with a delay of at least 3 hours; this has a significantimpact on the composition of both residual melt and new-Plgs. For undercooling>35 °C the Cpx delay causes a strong supersaturation of this phase in the melt resulting ina decrease in the new-Plg nucleation rate by 2 orders of magnitude in the 3 h-experiment.In the 15h-run, Cpx coarsening and the decrease of crystallinity suggest the achievementof a near-equilibrium conditions. Cpx growth rate is in the order of 10-7 cm·s-1 showingvery limited variation. Finally, for the investigated superheating (5-15 °C) only the longlasting experiments allows an estimation of Plg dissolution rate (10-9 cm·s-1) althoughchanges in the melt composition are already detectable in the 3h-runs.As a whole our results suggest that in natural systems, the takeover of antecrysts/xenocrysts by a magma can induce on a short time scales, changes in its initial nucleationbehavior with remarkable petrological implications for the solidification paths anderuptive dynamics of potassic magmatic systems.

Experimental cannibalization of plagioclase by alkaline basalt magmas

Conte A. M.
2023

Abstract

Time-series crystallization/dissolution experiments were conducted on a natural potassicbasalt seeded with bytownitic plagioclases (Plg) at atmospheric pressure, in air, at 1180-1240 °C and isothermal dwell time up to 20 hours. Plg-seed presence promotes the earlyformation of new-Plg, dampening the clinopyroxene (Cpx) crystallization. New-Plgsgrow at a rate from 10-6 up to 10-8 cm·s-1 as the dwell time increases. Seeds overgrowat similar rate. Cpx crystallizes with a delay of at least 3 hours; this has a significantimpact on the composition of both residual melt and new-Plgs. For undercooling>35 °C the Cpx delay causes a strong supersaturation of this phase in the melt resulting ina decrease in the new-Plg nucleation rate by 2 orders of magnitude in the 3 h-experiment.In the 15h-run, Cpx coarsening and the decrease of crystallinity suggest the achievementof a near-equilibrium conditions. Cpx growth rate is in the order of 10-7 cm·s-1 showingvery limited variation. Finally, for the investigated superheating (5-15 °C) only the longlasting experiments allows an estimation of Plg dissolution rate (10-9 cm·s-1) althoughchanges in the melt composition are already detectable in the 3h-runs.As a whole our results suggest that in natural systems, the takeover of antecrysts/xenocrysts by a magma can induce on a short time scales, changes in its initial nucleationbehavior with remarkable petrological implications for the solidification paths anderuptive dynamics of potassic magmatic systems.
2023
Istituto di Geologia Ambientale e Geoingegneria - IGAG
crystallization/dissolution experiments
disequilibrium
alkaline magma
heterogeneous nucleation;
plagioclase;
clinopyroxene
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/451854
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