In this work, a fast method for obtaining a quantitative elemental mapping of highly inhomogeneous samples by ?-LIBS maps is proposed. The method, transportable and cheap, allows the analysis of large maps through the use of a Self-Organizing Map clustering method coupled to Calibration-Free LIBS for quantification of cluster prototypes. The method proposed has been verified on heterogeneous materials such historical lime mortars but it can be easily applied to a larger class of inhomogeneous materials for very different applications (modern building materials, biological samples, industrial materials, etc.).

Fast quantitative elemental mapping of highly inhomogeneous materials by micro-Laser-Induced Breakdown Spectroscopy

Campanella B;Grifoni E;Legnaioli S;Lorenzetti G;Poggialini F;Palleschi;
2018

Abstract

In this work, a fast method for obtaining a quantitative elemental mapping of highly inhomogeneous samples by ?-LIBS maps is proposed. The method, transportable and cheap, allows the analysis of large maps through the use of a Self-Organizing Map clustering method coupled to Calibration-Free LIBS for quantification of cluster prototypes. The method proposed has been verified on heterogeneous materials such historical lime mortars but it can be easily applied to a larger class of inhomogeneous materials for very different applications (modern building materials, biological samples, industrial materials, etc.).
2018
Istituto di Chimica dei Composti OrganoMetallici - ICCOM -
Atomic emission spectroscopy; Biological materials; Calibration; Conformal mapping; Laser induced breakdown spectroscopy; Lime; Mortar
Biological samples; Calibration free; Clustering methods; Elemental mapping; Heterogeneous materials; Industrial materials; Inhomogeneous materials; LIBS
Self organizing maps
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/452974
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