For eight HCO+ rotational transitions we compare semiclassical and quantum calculations of the line broadening and shift induced by collisions with argon and helium atoms. A detailed analysis of the results allows better insights into the problem of the accuracy of the semiclassical model commonly used in most line shape studies.

Comparison between semiclassical and quantum calculations for collisional broadening and shift of HCO+ rotational lines

Buffa G
2007

Abstract

For eight HCO+ rotational transitions we compare semiclassical and quantum calculations of the line broadening and shift induced by collisions with argon and helium atoms. A detailed analysis of the results allows better insights into the problem of the accuracy of the semiclassical model commonly used in most line shape studies.
2007
Istituto per i Processi Chimico-Fisici - IPCF
molecular spectroscopy
collisions
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Descrizione: Comparison between semiclassical and quantum calculations for collisional broadening and shift of HCO+ rotational lines
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/46485
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