It is well established that water plays a fundamental role in various atmospheric phenomena and that the accuracy of its collisional broadening parameters has a crucial influence on reduction of remote sensing data. Nevertheless, in this field the experimental data are still scarce and consequently the estimates reported in spec- troscopic databases are not always reliable and/or accurate. In the view of filling this gap, the self-, N2- and O2-broadening parameters of the J = 1,1,1 - 0,0,0 rota- tional transition of water (1.113 THz) have been determined at room temperature. The experimental investigation has also been supported by theoretical calculations.

Pressure-broadening in the THz frequency region: The 1.113 THz line of water

Buffa G;
2008

Abstract

It is well established that water plays a fundamental role in various atmospheric phenomena and that the accuracy of its collisional broadening parameters has a crucial influence on reduction of remote sensing data. Nevertheless, in this field the experimental data are still scarce and consequently the estimates reported in spec- troscopic databases are not always reliable and/or accurate. In the view of filling this gap, the self-, N2- and O2-broadening parameters of the J = 1,1,1 - 0,0,0 rota- tional transition of water (1.113 THz) have been determined at room temperature. The experimental investigation has also been supported by theoretical calculations.
2008
Istituto per i Processi Chimico-Fisici - IPCF
pressure broadening
pressure shift
relaxation
rotational transition
water
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/47497
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