Influence of changing water mass circulation on detrital component and carbon burial of late Pleistocene and Holocene sediments in the eastern-central Mid-Adriatic deep

A sediment core was retrieved in the eastern-central Mid-Adriatic Deep (MAD) to study the changes in the water mass circulation and their effect on carbon burial efficiency and the provenance of a detrital sediment component. An age-depth model of the sediment core POS-514-40-11 is based on radiocarbon dating and tephrochronology. Two tephra were correlated to the Neapolitan Yellow Tuff and Pomici di Mercato eruptions, extending the previously known distribution of Pomici di Mercato tephra. Based on the analysis of heavy mineral (HM) assemblages throughout the core, for the first time the occurrence of Eastern Adriatic current (EAC) was estimated at ca. 15 ka BP, i.e., at the beginning of the post last glacial maximum (LGM) transgression. During the late Pleistocene, the detrital component was dominated by Paleo-Po river sediments, which gradually shifted toward the Albanian province as a basin-wide counterclockwise circulation was established. Mass accumulation rates of organic carbon (OC), stable isotopes of carbon (8 13C) and nitrogen (8 15N) as well as C/N ratios, showed that carbon burial was affected by sea level rise and climatic changes. Climatic effects are observed during cold periods i.e., the Younger Dryas and the 8.4-7.9 ka cold period when terrestrial OC was dominant. In the latter case dominance of terrestrial carbon was due to the North Adriatic dense water (NAddW) influence. On the other hand, sea level rise increased MAD distance from the main river mouths/deltas, resulting in decreased influx of terrestrial organic carbon and lower accumulation rates of organic carbon in general. This reconstruction of the oceanographic setting is valuable considering that the Adriatic Sea is one of the key locations for the formation of DW and thus affects the overall Mediterranean circulation.