X-ray Investigation of CsPbI3:EuCl3 Infiltrated into Gig-Lox TiO2 Spongy Layers for Perovskite Solar Cells Applications

In this study, we explore the potential of a blended material comprising (Formula presented.) : (Formula presented.) perovskite and Gig-Lox (Formula presented.), a unique transparent spongy material known for its multi-branched porous structure, for application in solar cells. The inclusion of (Formula presented.) in (Formula presented.) serves to stabilize the photoactive (Formula presented.) -phase with a bandgap of 1.75 eV, making it suitable for solar energy conversion in tandem solar cells. Our study applies X-ray-based techniques to investigate the structural properties and interfacial behavior within this blended material, in comparison with a reference perovskite layer deposited on glass. In addition, Spectroscopic ellipsometry is complemented with density functional theory calculations and photoluminescence measurements to elucidate the absorption and radiative emission properties of the blend. Notably, our findings reveal a significant quenching of photoluminescence within the blended material, underscoring the pivotal role of the distributed interfaces in facilitating efficient carrier injection from the (Formula presented.) : (Formula presented.) perovskite into the Gig-Lox (Formula presented.) sponge. These findings pave the way for the application of the blend as an Electron Transport Layer (ETL) in semi-transparent perovskite solar cells for tandem and building integrated photovoltaics.