Wastewater pollution caused by toxic dyes from the textile industry is a global challenge, threatening agricultural productivity, food security, and access to clean water for livestock. In recent years, photocatalytic degradation of organic pollutants using semiconducting materials has emerged as a promising approach for sustainable wastewater treatment. We present a cost-effective synthesis method for lithium manganese oxide (Li2MnO3), which aggregate to form a densely packed microcrystalline powder, with smooth-stone morphology, and monoclinic crystal structure. Optical characterization reveals broad visible light absorption, strong infrared reflectance and an optical bandgap of 2.1 eV, suggesting potential applications in radiation-resistant coatings. Moreover, the obtained Li2MnO3 material effectively degraded Eriochrome Black T, a common textile dye, with efficiencies up to 73% for 5 × 10⁻5 M solutions, under illumination at 625 nm, within 60 min. These findings underscore the potential of Li2MnO3 nanostructured microcrystals for wastewater treatment applications.

Lithium Manganese Oxide (Li2MnO3) as a promising photocatalyst for the degradation of Eriochrome Black T

Marco Villani;Valentina Sinisi
;
Stefano Rampino;Nicola Coppede;
2025

Abstract

Wastewater pollution caused by toxic dyes from the textile industry is a global challenge, threatening agricultural productivity, food security, and access to clean water for livestock. In recent years, photocatalytic degradation of organic pollutants using semiconducting materials has emerged as a promising approach for sustainable wastewater treatment. We present a cost-effective synthesis method for lithium manganese oxide (Li2MnO3), which aggregate to form a densely packed microcrystalline powder, with smooth-stone morphology, and monoclinic crystal structure. Optical characterization reveals broad visible light absorption, strong infrared reflectance and an optical bandgap of 2.1 eV, suggesting potential applications in radiation-resistant coatings. Moreover, the obtained Li2MnO3 material effectively degraded Eriochrome Black T, a common textile dye, with efficiencies up to 73% for 5 × 10⁻5 M solutions, under illumination at 625 nm, within 60 min. These findings underscore the potential of Li2MnO3 nanostructured microcrystals for wastewater treatment applications.
2025
Istituto dei Materiali per l'Elettronica ed il Magnetismo - IMEM
Synthesis, Li2MnO3, Photocatalytic degradation, Eriochrome Black T, Dye, Wastewater
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/543183
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