Inverse-Doped Melt-Textured Gd1212 Superconductors Samples: Normal State Raman Characterisation Study

Gd1212 (GdSr2RuCu2O8-y) is a superconductor, isostructural to Y123 (YBa2Cu3O7-x), whose high interest is due to the coexistence of superconducting and magnetic ordered phases in the same unit cell. Up to now the best superconducting properties for Gd1212 have been achieved by TSG (Top-Seeded Melt-Textured growth), a well-known technique used to grow high quality samples from High Temperature Superconductors characterized by a peritectic melting reaction. Due to the relevant production of liquid during the melting of Y123-like materials, the standard TSG procedure involves the addition of secondary phases in the starting powders mixture, generally the peritectic solid phase or one of its precursors, to enhance the structural stability of pellets during the process. This practice also provides additional pinning centers in the final samples, improving their Superconducting features. Unfortunately, Gd1212 peritectic reaction produces an insufficient amount of liquid phase, so preventing from obtaining wide crystallographic domains, and the addition of the peritectic solid phase Gd1210 (GdSr2RuO6), although beneficial on the superconducting properties, even worsen this problem. In this work we tried to grow larger Gd1212 domains by inverting the usual approach: i.e., by adding in the precursor powders some peritectic liquid phase (CuO) instead of Gd1210. Anyway, previous analyses suggested us that the chemistry of Gd1212 melting may change for excess CuO mixtures. We have characterized the obtained samples by means of Raman spectroscopy and mapping, data were compared with those of Gd1210-doped and pure Gd1212 samples, results confirm our hypothesis of different melting reaction for CuO rich samples.